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Santoprene extracts contained higher concentrations of inorganic carbon and little, if any, extractable silicon On the other hand, the amount of silicone in extracts of silicone polymers was very high From Table 37, it is possible to see that these materials, though all made of silicone, are very different each other While about 100 g/g Si was found in the aqueous extract from sample 1, no measurable Si was detected in the same extracts from samples 2 and 6 As could be expected, silicone extractables were much higher in ethanolic extracts, being that 739 g/g Si from sample 6 was the lowest amount leached The analysis of aqueous and ethanolic extracts by techniques such as liquid chromatography mass spectrometry (LC MS) and CG MS showed that all silicon materials contained essentially the same peaks, that is, the same compounds were extracted The distribution, however, varied from material to material.

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Figure A-2

The primary organic extractables from silicone tubing were homologous series of silicone oligomers with the structural formula [(CH3)2SiO]n Direct matches with an MS spectral library allowed the identi cation of oligomers with n = 5 to n = 25 However, while in sample 3, the peaks were at the lower range of n, the oligomer distribution for sample 2 was shifted toward higher molecular weights, which are less soluble and therefore less extractable Figure 14 illustrates the differences in the ethanolic extracts of materials 2 and 3 Results of Santoprene extracts are quite different from those of silicone GC MS chromatograms for water extracts of Santoprene tubing show peaks associated with C8 and C9 acids, phthalates, and other organic substances.

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Photonic crystal bers are a new kind of optical ber that has microscopic holes running along the length of the ber and/or a hollow core in the center of the light guide, which give the ber advantages for transmitting information. By controlling the size and placement of the holes, it is possible to control the physical properties of the light as it propagates through the ber and/or the hollow core (light travels through air or a vacuum more e ciently than through glass or plastic). Photonic crystals can be employed in the manufacturing of holey bers. First holey- ber laser with Er-doped core, achieved lasing at 1535 nm with relatively high output and e ciency. Improved all-silica single-mode photonic crystal bers. Improved photonic crystal bers with small e ective area and larger nonlinearities; facilitate nonlinear optical processing e.g., supercontinuum generation, optical 2R regeneration, and optical code division multiple access (CDMA) using shorter bers and lower optical power levels. Supercontinuum generation of 400 1600 nm white light. Soliton generation with high peak power. Micro uidics applications with photonic crystal bers. Surface-emitting single-defect photonic crystal lasers. Polarization-controlled single-mode photonic crystal VCSEL using asymmetric holes to break the symmetry for single-polarization-mode operation. Microdisk lasers: ring laser coupled to optical bus, demonstrating that it can be integrated with other components. There has been a steady improvement in the techniques for quantum communications (i.e., the use of the constraints set by quantum mechanics to the measurement of two conjugate observables to device methods for secure communications).

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In an MPLS domain, a label-switched path LSP. can be established for a data stream using MPLS signaling protocols. At the ingress label switched router LSR., each packet is assigned a label and is transmitted downstream. At each transit LSR along the LSP, the basic function of the label is to map to the next hop in order to forward the packet w4x. In a Diffserv domain, all the IP packets traversing a common path and requiring the same Diffserv behavior constitute a behavior aggregate BA.. At the ingress node of the Diffserv domain the packets are classified and marked with a Diffserv codepoint DSCP., which corresponds to their BA. At each transit node, the DSCP is used to select the per-hop behavior PHB. that determines the scheduling treatment and, in some cases, drop probability for each packet. An ordered aggregate OA. is the set of BAs that share an ordering constraint. Because MPLS is path-oriented, it can potentially provide faster and more predictable protection and restoration capabilities in the face of topology changes than conventional hop-by-hop-routed IP systems. Such capabilities are referred to as MPLS protection, and they may offer different levels of protection to different LSPs. In order to support Diffserv over MPLS networks, the MPLS network administrator must have the flexibility to select how BAs are mapped onto LSPs so that one can best match the Diffserv, traffic engineering, and protection objectives within one s particular network.

Figure 15 shows the GC MS chromatograms of static ethanol extracts of Santoprene tubing materials, and Table 38 lists the compounds identi ed in Figure 14, based on matches of MS spectrum peaks 6134 Particulate Matter.

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